2053.質(zhì)子化酞菁銥配合物的光譜調(diào)控研究

1、學校代碼：10270分類號：O61學號：142200687碩士學位論文質(zhì)子化酞菁銥配合物的光譜調(diào)控研究學院：生命與環(huán)境科學學院專業(yè)：無機化學研究方向：光功能材料研究生姓名：鄧晶晶指導教師：楊紅教授完成日期：2017年3月上海師范大學碩士學位論文AbstractIIIAbstractWiththedevelopmentofphotoelectrictechnologyphthalocyaninehasbeenwidelyappliedin

2、thefieldofLBfilmopticalstagemediumenergyconversionmaterialssemiconductsetc.Inthispaperwesynthesizedaprotonatedphthalocyanineiridiumcomplex(IrPcHCl2)focusingonaseriesoffactstocontroltheabsptionspectrumitsmechanismffurther

3、study.Themaincontentsincludethefollowingthreeaspects.1.SpectralRegulationofIrPcHCl2bysolventconcentrationTheiridiumcomplexeswithphthalocyanineastheligweredesignedsynthesized.ThestructuresofIrPcHCl2wereacterizedby1HNMRhig

4、hresolutionmassspectrometry.TheabsptionspectrainCH2Cl2CHCl3THFDMSODMFCH3CNweretested.TheresultsshowthatthesymmetryoftheprotonatedphthalocyanineringchangesmakingtheQbofIrPcHCl2split.IrPcHCl2showeddeprotonationinDMSODMFCH3

5、CN.TheeffectsofconcentrationonIrPcHCl2spectrawerestudied.TheconcentrationofIrPcHCl2didnotoccurintheexperimentalconcentrationrange.2.SpectralregulationofIrPcHCl2byacidTheeffectsofCF3SO3HCF3CO2HontheabsptionspectraofIrPcHC

6、l2werestudiedinTHFCH2Cl2benzonitrile.TheresultsshowthatthestrengthoftheacidthepolarityofthesolventaffecttheprotonationofIrPcHCl2whichcancausethechangeoftheabsptionspectrum.3.SpectralregulationofIrPcHCl2bysilversaltThewki

7、nthissectionrevolvesaroundthespectralcontrolofIrPcHCl2infoursolvents(AgBF4CF3SO3AgCH3COOAgCF3COOAg)intwosolvents.Duetotheanionofthealkalinecodinationcapacityofthedifferencescausedbychangesinthespectrum.Howeverothermetali