金屬酞菁軸向配合物的合成及性質(zhì)的研究.pdf

1、東北師范大學(xué)碩士學(xué)位論文金屬酞菁軸向配合物的合成及性質(zhì)的研究姓名：牛效迪申請(qǐng)學(xué)位級(jí)別：碩士專業(yè)：物理化學(xué)指導(dǎo)教師：傅強(qiáng)20050501AbstractPhthalocyaninesandmetalophthlocyanineshavebeeninvestigatedformanyyearsinmuchdetailTheyhavebeenmostlyfocusedattentionuponintheareaofoptics，electri

2、cityandmagneticmoleculePhthalocyaninesandstructurallyrelatedcompoundsareofinterest，forexample，innonlinearoptics，aselectrochromicsubstances，aslow—dimensionalmetals，inmctifyhagdevices，asgassensors，asphotosensitizersandasca

3、rriergenerationmaterialinNIRInthispaperwearesupposedtosynthesizethesubtitutionalphthalocyaninatometalaxiscomplex，whichis24，6一Trimethyl—phenoxyphthalocyaninatometal，Basedonthebenzdnitrilemethod，throughthenituation，substit

4、ute，wesynthesizethe4(2，4，6Trimethylphenoxy)phthalonitrileWiththereactionofthephthalonitrleandthemetalsalt，substitutionalphthalocyaninatometalissynthesizedBecauseofthesubstituteofthephenoxythesolubilityofthephthalocyanlna

5、tometalisgreatlyimprovedintheorganicsolventInthispaperphthalocyaninatometalaxiscomplexissynthesized、ⅣitIlthesolvothmaimeans，whichisnotreportedinancientlyliteratureAsaresnlt，unsubtitutionalphthalocyaninatometaiaxiscomplex

6、isgainedThereasonisthatC0banmotsteadyin160。Candhi曲pressureInthesynthesisofthesubtitutionalphthalocyaninatometalaxiscomplexthroughthisnewmethod，howeverwehavetostudythemethodItCanbeseenfromtheUVvisofthesubtitutionalphthalo

7、cyaninatometalthattheQbandofphthaloeyaninatometaliseinsteinshift、ⅣiththesuhtitutionalgroupandBbandofphthalocyaninatometalbroadensgreatlyIntheUVvisofthesubtitutionalphthalocyaninatometalaxiscomplex，theQbandofphthalocyanin

8、atometalaxiscomplexiseinsteinshiftmorethan4nnlcomparingwiththephthalocyaninatometalTheahsorptiometerismorenarTowthanbeforeTheopticalpropertyofthedyeCaD_beimprovedi1“1acertainextentKeywards：phthalocoyaninatometal；complex；