Ⅰ全氟磺酰氟樹脂負載的鈀催化劑的合成與應用Ⅱ己二酸的綠色合成.pdf

1、復旦大學碩士學位論文Ⅰ全氟磺酰氟樹脂負載的鈀催化劑的合成與應用Ⅱ己二酸的綠色合成姓名：連慧申請學位級別：碩士專業(yè)：有機化學指導教師：丁宗彪20030520復旦大學碩士學位論文Abs訂actAbstractWiththerapiddevelopmentof“green’’chemistryscientistshopethatinorganicoxidations，watercatlreplaceorganicsolvents，and“gr

2、eenoxidants”suchasairoxygenorhydrogenperoxideCanreplacetraditionaloxidantsthatcarlgeneratecopiOUSamountsofwasteandpollutionMucha囂entionhasbeendrawntocatatyticoxidations，oneofthemostimportantreactionforfimctionalgrouptran

3、sformationinorganicsynthesisNowadays，theresearchemphasishasrecentlyswitchedtothesearchfornovelcatalystswithhighactivityhighstabilityandeasyrecoveryInthisthesiswemainlydiscusstwokindsofworkthatisassociated晰m“green”chemist

4、ryOneisthesynthesisandapplicationofperfluorinatedpolymer—supportedPd(II)catalysts，theotheristhesynthesisofadipicacidwitha“green”routePolymersupportedcatalystsareadvantageousoverthetraditionalonesinmanyaspects，suchaseasys

5、eparationfromthereactionmixtureandrecyclingTheapplicationofPolymersupportedcatalystsisaclearexampleof“green”chemistryinwhichthewastestreamsanddepletionofresourcesassociatedwithtransitionmetalsisminimized，Inthefirstpartof

6、thethesis，thepeffluorinatedpolymersupportedPd(II)catalystswereprepared，andtheirapplicationintheoxidationsofalcoholshasbeeninvestigatedWiththeassistanceofmicrowave，5amino一1，10phenanthrolineandalso4aminopyridinewerecovalen

7、tlylinkedtotheperfluorinatedpolymerNationTwoPd(II)catalysts(8，卵wereobtainedbycoordinationeffectsofPd(II)saltswiththeattachedligandsThecatalyticactivitywereassessedusingtheoxidationreactionofalcoholstocarbonylcompoundsOur

8、resultsexhibitedthataromaticalcoholscaIlbeoxidizedtothecorrespondingketonesoraldehydesefficientlyusingthenovelPd(II)catalystswhilstaliphaticalcoholsbehavedpoorlyItWasfoundthatbothofthecatalystSarereusableatleast5timesOth

9、erwise，tentativelywesynthesizedcatalyst10whichwastheproductofcoordinationeffectsofPd(II)saltsandpolystyrene—bound4aminopyridineAdipicacidisnecessaryforthemanufactureoffibres，andtheindustrialprocessesofitsproductionCangen