1，8-萘酰亞胺配體及其配合物的合成、結(jié)構(gòu)與性質(zhì)研究.pdf

1、青島科技大學(xué)碩士學(xué)位論文1，8萘酰亞胺配體及其配合物的合成、結(jié)構(gòu)與性質(zhì)研究姓名：杜麗申請(qǐng)學(xué)位級(jí)別：碩士專(zhuān)業(yè)：物理化學(xué)指導(dǎo)教師：建方方20090605THESYNTHESIS，CRYSTALSTRUCTUREANDPROPERnESDn廠ESTIGATIONSON18NAPHTHALIMIDDEDERVIATIVESABSTRACTTwoorganicligandsofimidazolesbaseon18一Naphthalimideder

2、viativesandtenSchiffbaseon18Naphthalimidederviativeshavebeensynthesizedandcharacterizedbyelementalanalysis，IRspectra，UVspectra，1HNMRspectra，andsinglecrystalXraydiffractionThreesiglecrystalstructuresoftheligandshavebeende

3、terminedTheyare6Oxobenz[de]isoquinolino[2，1一a]benzimidazoliumchloridemonohydrate(2a)，N(2Hydroxybenzylideneamino)l，8naphthalimide(3a)，and4一B卜N(pphenylenediaminesalicylaldehyde)一18naphthalimide(3h)Thefluorescenceproperties

4、havebeenstudiesbySolidStateFluorescenceapproach，andtheresultsindicatethatthefluorescentintensitiesof6Oxobenz[de]isoquinolino[2，l—a]benzimidazoliumchloridemonohydratehavestrongintensities，andtheyaregoodfluorescentcompound

5、sBut，4Br6一Oxobenz[de]isoquinolino[2，1a]一benzimidazoliumchloridemonohydratehavebeenvanishedbythemselvesTwentymentalcompoundsweresynthesizedusingtwoligandsoftheN(2一Hydroxybenzylideneamino)一1，8一naphthalimide(3a)and4BrN(pphe

6、nylenediaminesalicylaldehyde)一1，8Naphthalimidederviatives(3h)Thesecomplexesweresynthesizedviathereactionoftheligandswithhalideoftransitionmetal，suchasNi(II)，Cu(II)，Co(II)，Zn(II)，F(xiàn)e(II)inratioof2：1，andthencharacterizedbye

7、lementalanalysisandIRspectraThecomplexesforCu(n)，co(r0Ni(II)of(3a)andcu(n)of(3h)wereobtainedandcharacterizedbyelementalanalysis，IRspectra，UVspectraanalysis，andTG／DTGThecrystalstructureofcomplexes[C44H36CuN60s](4a)and[C44