含咪唑基配位聚合物的設(shè)計(jì)、合成、晶體結(jié)構(gòu)和性質(zhì)研究.pdf

1、擘縋吠學(xué)碩士學(xué)位論文含哮唑基配位聚合物的設(shè)計(jì)、合成、昌體結(jié)構(gòu)和性質(zhì)研究DesIgn，s，nthesis，o’ystⅢs”uctures8ndProper“esofImIdⅡ肋le—containi峰CoordInationPoIymers姓名學(xué)科專(zhuān)業(yè)研究方向指導(dǎo)教師完成時(shí)間金鳳無(wú)機(jī)化學(xué)功熊配臺(tái)物吳杰額教授田玉鵬教授20。5年5月窒墼查蘭堡主堂垡堡苧壘墾一一一一——ABSTRACTThecrystalengineeringofone一，t

2、w0一，orthree—dirnensionalcoordinationpolymershaSattractedconsiderablecurrenta吮ntion，notonlybecauseofthcirnoVeltopologiesandf弧cinatingStmcturaldiVersities，butalsofortheirpotemiaIapplicationsinoptical，elec喇cal，magnetic，aIld

3、catalysisetcInthispaper，aseriesofD吼Astructureimidazolederivat沁esweresynthesiZed，舢過(guò)manycoordinationpolymerswefealsosynthesizcdviasupramoleculeself_assemblyWeObtained廿lesinglecrystalsoftlleconlplexesarldinvestigatedtherela

4、tionsllipsbetweenthestructuresandpmpemesindetailThetllesisincludesfourcIlapIers：Inthefirstcllapter山erecentprogressoftheimi出lzolecontainingcoordinationp01ymershavebeenreviewedexteIlsivelyb躺ed0nmedetailedinVestig砒ionofrela

5、tedliteraturcsTheprogressofN—HeterocyclicCarbenes(NHC)anditscomplexeshavealsobeenreviewedIn也eseconddlaptetaseriesofimiazoled甜vatives誦也D幔一AstructuresweresymhesizedThecompounds、Ⅳerem11ycharacterizedbyIR，EMS，1HNMRspectraele

6、mentala11alysisandsinglecrystal)(raydifn乜ctiondeteminationsetc’nleligarIdscanreact晰thtrallsitionmctaltlliocyaIl8tes，several妯1dsofc00rdinationpolymerSwereobtainedThestructuralcharacteristicsoft11ecomDlexeshavebeendescribe

7、dindetailbasedontheresuhsofsin斟e(cuò)crystalX—raydi鼢ctiondcte眥inationSInthet11irdch印ter’tllepropertiesofmecompollIldshavcbeenstIldiedmrelationshipsbetweenstnlcturesandpropenieshavebeendiscussedindetailInthe1astchapteraserieso

8、fimidazoliumsweresynthesizedandcharacterizedIn∞nclusion，as商esofimidazolecon詛iningcoordin砒ionp01ymershavebecnsynthesizedandstudiedinthethesisKeywords：supramoIecuIe，coordinationpoIymercrystalengineerin備imidazole，thiocyanat