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1、ARTICLEINPRESSWaterResearch38(2004)33403348IntegratedrealtimecontrolstrategyfnitrogenremovalinswinewastewatertreatmentusingsequencingbatchreactsJuHyunKimaMeixueChenbNaohiroKishidacRyuichiSudoaaCenterfEnvironmentalScience
2、inSaitama914KamitanadareKisaiSaitama3470115JapanbStateKeyLabatyofEnvironmentalAquaticChemistryResearchCenterfEcoEnvironmentalSciencesChineseAcademyofSciencesBeijing100085P.O.Box2871ChinacDepartmentofEnvironmentalResource
3、sEngineeringWasedaUniversity341OkuboShinjukukuTokyo1698555JapanReceived7May2003receivedinrevisedfm29March2004accepted11May2004AbstractAnewintegratedrealtimecontrolsystemwasdesignedoperatedwithfluctuatinginfluentloadsfswi
4、newastewatertreatment.Thesystemwasoperatedwithautomaticadditioncontrolofanexternalcarbonsourceusingrealtimecontroltechnologywhichutilizedtheoxidationreductionpotential(P)thepHasparameterstocontroltheanoxicphaseoxicphaser
5、espectively.ThefluctuationsinswinewastewaterconcentrationareextremeaninfluentwithalowC=Nratioisdeficientinganiccarbonalowcarbonsourcelevelcanlimittheoverallbiologicaldenitrificationprocess.Consequentlyasufficientganicsou
6、rcemustbeprovidedfproperdenitrification.Thefeasibilityofusingswinewasteasanexternalcarbonsourcefenhancedbiologicalnitrogenremovalwasinvestigated.Therealtimecontrolmadeitpossibletooptimizethequantityofswinewasteaddedasthe
7、loadfluctuatedfromcycletocycle.TheaverageremovalefficienciesachievedfTOCnitrogenwereover94%96%respectivelyusingtheintegratedrealtimecontrolstrategy.r2004ElsevierLtd.Allrightsreserved.Keywds:DenitrificationExternalcarbons
8、ourcePRealtimecontrolSBRSwinewastewater1.IntroductionSwinewastewaterhaspreviouslybeenconsideredasoneofthemajsourcesofnitrogenpollutiondisgedintotheenvironment.Traditionalbiologicalremovalofnitrogenwasachievedbyasequenceo
9、fnitrificationdenitrificationprocesses.Sincethefluctuationsinswinewastewaterconcentrationareextremeduetothevaryingpracticesofmanuremanagementinrecentyearstherealtimecontrolprocessusingoxidationreductionpotential(P)pHaspa
10、rameters(Loetal.1994PlissonSauneetal.1996Crespondingauth.Tel.:81480738369fax:81480702031.Emailaddress:(J.H.Kim).Chapentieretal.1998Fuerhackeretal.2000)tocontroltheoxicanoxiccyclesofasystemhasreceivedmuchattentionfswinewa
11、stewatertreatment(Raetal.19981999Tilcheetal.2001)insequencingbatchreacts(SBRs).ComparedtothetraditionalprocessrealtimecontrolstrategyfabatchtreatmentprocessusingPpHwasselfadjustedtovarioustreatmentconditionssuchasinfluen
12、tstrengthtreatmentstatus.Thisresultedinflexiblehydraulicretentiontime(HRT)fromcycletocycle(Raetal.2000).Thehighstableremovalrateofnitrogenwasalsoachieved(Raetal.1998Chengetal.2000).AlthoughrealtimecontrolstrategybasedonP
13、pHhasbeenappliedtomanyswinewastewatertreatmentsystemsuntilnowthesuccessofthesystemshasnotbeenconvincingbecausemuchefftinthe00431354$seefrontmatterr2004ElsevierLtd.Allrightsreserved.doi:10.1016j.watres.2004.05.006ARTICLEI
14、NPRESS3342J.H.Kimetal.WaterResearch38(2004)33403348ThePpHDOprobeswereedintotheSBR.Theoutputsignalwasdirectedtoacomputer.Theinfluentpumpeffluentpumpaeratagitatswinewastepumpwerecontrolledbyarelayboxconnectedbyelectricalca
15、ble.OurexperimentwasstartedwithhighC=Nratioload(TOCTN1.5)influentwhichwascollectedafterscreeningtreatment.Afteroneweekofoperationthefluctuatinginfluentwascontinuouslyusedf8monthsinourexperiment.Swinewasteasanexternalcarb
16、onsourcewasaddedintotheSBRfcompletedenitrificationafteratimedeterminedbyourexperimentiftherewasinsufficientcarbonsourceintheinfluent.Fthepurposeofeasyautomaticcontrolapulsedinputpatternofswinewastewasusedtocompensatefthe
17、externalcarbonsource.DuringlowC=NloadinfluentcyclesthedilutedswinewastewaspumpedintotheSBRbyapulsemeteringpumpwithapulseof1gcyclethetimeintervalbetweenadditionswasdesignedtobe10min.Ifthequantityofswinewasteaddedwasdefici
18、entfcompletedenitrificationthenextadditioncyclewasstartedwhenthenitratekneepointwhichindicatestheendofdenitrificationappearedonthePprofiletheadditionofswinewastewasstopped.Therefethequantityofswinewasteaddedadaptedtofluc
19、tuationsinthewastewatertheoptimizationwaseasilyachievedbythepulsedinputpattern.2.2.InfluentswinewastewaterwasteseedsludgeTheswinewastewaterusedinthisstudywasobtainedfromalocalfarminSaitamaJapan.Thepracticalswinewastewate
20、rwithhighC=Nratio(TOCTNratio:methan1.2)lowC=Nratio(TOCTNratio:lessthan0.8)whichwasobtainedbefeaftercoagulationtreatmentrespectivelywasusedalternatelyintheexperiment.TheC=Nratiooftherawwastewaterwasmarkedlychangedbythesep
21、arationoffecesurine.TheTOCTNratiointhewastewaterwasvariedintherangeof0.451.53.Theswinewastewaterwasstedat4Cuntilrequired.Theswinewastewasobtainedfromthesamefarm.Pritousethewastewasscreenedusingasievewith0.5mmmeshopenings
22、toremovelargesolidsdilutedwithtapwaterthenusedasanexternalcarbonsourceinlowC=Nratioloadperiodsfcompletedenitrification.TheacteristicsofthedilutedswinewastearelistedinTable1.Theaverageconcentrationofmixedliqususpendedsoli
23、ds(MLSS)inthesystemwasmaintainedatapproximately7000mgL1.WhentheconcentrationofMLSSinthereactwasmethan8000mgL1sludgewasdrawnout.DuringtheexperimentperiodtheaverageSRTwas32days.Table1acteristicsofthedilutedswinewasteParame
24、tersMeanMinmaxStd.dev.mgL1(n15)TOC26167114105564017010BOD5902804637017220031850TN4529241868821741TP260015003810821TSS9172403950437202.3.SamplinganalyticalmethodsParametersroutinelyassayedincludedTOCBOD5totalnitrogen(TN)N
25、H4NNO3NNO2Ntotalphosphous(TP)PO4PMLSSmixedliquvolatilesuspendedsolids(MLVSS)totalsuspendedsolids(TSS).TrackanalysisthatcoveredtheentirecyclewascarriedoutathighlowC=Nratioload.Mixedliqusamplesweretakenduringtrackanalysis.
26、AnalysisfNH4NNO3NNO2Nwascarriedoutfeachtrackstudy.AnalysisfBOD5TSSMLSSMLVSSwasperfmedinaccdancewiththestardmethod(APHA1995).TheNH4NNO3NNO2NPO4Pwereanalyzedwithanionchromatograph(YokogawaIC7000).TheTOCwasanalyzedwithaShim
27、adzutotalganiccarbonanalyzer(TOC5000).TNTPwereanalyzedwithatotalnitrogenphosphousanalyzer(TN30TP30MitsubishiChemicalCp.)3.Resultsdiscussion3.1.RealtimecontrolpointinhighCNratioloadcyclesInhighC=Nratioloadcycleswithrealti
28、mecontroltechnologyusingPpHasanoxicoxiccontrolparametersatreatmentprocesscanbeoperatedeffectivelywithouttheadditionofanexternalcarbonsourcetoenhancethedenitrification.DuringtheinitialperiodwiththehighC=Nratioloadinfluent
29、relativeconstantfinaleffluentswereobtainedalongwithhighnutrientremoval.ThetypicalcontrolsetpointsareshowninFig.2.PointAisthefeedingpointafter5mintheanoxicphasewasstarted.FromthenutrientprofileitcanbeseenthatNO3Niscomplet
30、elydenitrifiedtonitrogengasthroughNO2Nwithin75minusingtheinfluentganicmaterialsasacarbonsource.PointBisknownasthenitratekneeinthePcurvewhichrepresentsthecompleteremovalofnitrate.Reptedlysulfatereductionthatproducessulfid
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