延遲交調(diào)剖技術及機理研究.pdf

1、大慶石油學院碩士學位論文延遲交調(diào)剖技術及機理研究姓名：周高寧申請學位級別：碩士專業(yè)：化學工藝指導教師：李柏林20070322StudytechnologyofdelaycrosslinkingforprofilecontrolandthemechanismofkineticsAbstractThispaperdiscussedthesynthesisconditionsoftheorganicaluminum，organicchromi

2、um。watersolublephenolicresinscrosslinkerItresearcheddifferentsynthesisconditionsforgelsanalyseddifferentfactorsthateffectedthegelperformance，suchas：systemcomponentthepHvalue，salinityItresearchedtheproblemofproportionands

3、ynthesisconditionsforthecomplexcrosslinkingsystemsFinallyitinquiredintothemechanismofkineticforthedifferentgelssystemInsynthesisofcrosslinkingagents，thebestratiooforganicaluminumcrosslinkeriSthataluminumion：Lactateacid：c

4、itrateacid=l：I：O3(reel)。thebestratiooforganicchromiumcrosslinkerjSthatchromiumion：1aerateacid=1：3Watersolublephenolicresincrosslinkingagentsynthesizedbythetwoalkalieatalyticsynthesisthebestratioofphenol：formaldehyde=l：25

5、IIlAl”，HPAMgelsystem，bestratioofsystemcomponentsbeused：polymers2000mg／L，crosslinkingagent100m∥L，pH7InC，／HPAMgelsystem，bestratioofsystemcomponentsbeused：polymers3000mg，L，crosslinkingagent200mg／L，releasingagentoxalicacid30

6、m∥L，pHrange59Inaqueousphenolicresineresslinkingagent／HPAMgelsystem，bestratioofcomponentsbeused：3000mg／Lpolymers。cresslinker500mg，L，itcanbeobtalnedbetterresultsunderalkalineCOnditionsGelsperformanceisimprovedsignificantly

7、foraqueousphenolicresin—aluminumcompositeacomplexcrosslinkedgelsystemThebet￡erofitsratioused：polymer2000mg／L，thecrosslinker300m∥L，organicaluminumwatersolublephenolicresinincomponentscrosslinkingagentratio3：2organicalumin

8、umorganicchromiumcgmpoundsforthecrosslinkingagent，thegelwillsignificantlybroadentheseepeofapplicationofpHItcanbeusedundertheconditionsofpH49。crosslinker200mg／L，polymer2000medLorganicaluminumandorganicchromiumcrosslinkerr

9、mio3：2Withtheincreaseinpolymerconcentration，gellingtimeShorcened，thegelstrengthincreasedAsthecrosslinkerconcentrationincreasesystemspeedgel，gelstrength，Butgenerallyleadtoexcessivecrosslinkingagentsystemisunstableandeasil

10、ydehydrationCrosslinkingsystemweredifferentforthedifferentpHvalueUsin2binarycomplexesAIchromeazurolSPhotometrytodeterminatedthereactionofaluminumcontentitCanbeceaifiedthatthereactionoforganicAIandpolymergelsystemislevel；

11、Useingofpolymerviseositytoorganicchromiumandtheapparentformationofcrosslinkedgelkineticequationr=K[HPAM]064【M】120，DeterminationoftheviscosityofwatersolublephenolicresinandpolymercrosslinkingreactionzeroleveIreactionsyste